A novel dicationic system containing a PN fragment has been synthesized and structurally characterized. According to the solid-state analysis and theoretical investigation, the dicationic iminophosphane resonance form is the most appropriate description for the dication. However, the contribution from the phosphorus mononitride resonance form is not negligible.
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| http://dx.doi.org/10.1021/acs.inorgchem.5b00003 | DOI Listing |
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