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Ternary Ag/MgO-SiO2 catalysts for the conversion of ethanol into butadiene.
ChemSusChem
March 2015
Centre for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, 3001 Leuven (Belgium), Fax: (+32) 1632-1998.
Ternary Ag/MgO-SiO2 catalysts for the conversion of ethanol into butadiene.
ChemSusChem
March 2015
Centre for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, 3001 Leuven (Belgium), Fax: (+32) 1632-1998.
Ternary Ag/Magnesia-silica catalysts were tested in the direct synthesis of 1,3-butadiene from ethanol. The influence of the silver content and the type of silica source on catalytic performance has been studied. Prepared catalysts were characterized by (29) Si NMR, N2 sorption, small-angle X-ray scattering measurements, XRD, environmental scanning electron microscopy with energy dispersive X-ray analysis (ESEM/EDX), FTIR spectroscopy of adsorbed pyridine and CO2 , temperature-programmed desorption of CO2 and UV/Vis diffuse reflectance spectroscopy.
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