A Single-Chain Magnet Tape Based on Hexacyanomanganate(III).

Angew Chem Int Ed Engl

Department of Chemistry, Texas A&M University, College Station, TX 77842 (USA) http://www.chem.tamu.edu/rgroup/dunbar/

Published: May 2015

The tape-like chain {[(tptz)Mn(II) (H2 O)Mn(III) (CN)6 ]2 Mn(II) (H2 O)2 }n ⋅4n MeOH⋅2n H2 O based on the anisotropic building block hexacyanomanganate(III) exhibits long-range magnetic ordering below 5.1 K as well as single-chain magnetic behavior at lower temperatures with an effective energy barrier of 40.5(7) K.

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http://dx.doi.org/10.1002/anie.201410664DOI Listing

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