VO2 (B) nanorods with average width ranging between 50-100 nm are synthesized via a hydrothermal method and the post hydrothermal treatment drying temperature is found to be influential in their overall phase and growth morphology evolution. The nanorods with unusually high optical bandgap for a VO2 material are effective in enhancing the thermal performance of ethylene glycol nanofluids over a wide temperature range as is indicated by the temperature dependent thermal conductivity measurements. Humidity and LPG sensors fabricated using the VO2 (B) nanorods bear testament to their efficient sensing performance, which can be partially attributed to the mesoporous nature of the nanorods.
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http://dx.doi.org/10.1039/c4nr06032f | DOI Listing |
Materials (Basel)
November 2024
NANOTECH Centre, Ural Federal University, Mira Str., 19, 620002 Ekaterinburg, Russia.
Nanotubular hafnia arrays hold significant promise for advanced opto- and nanoelectronic applications. However, the known studies concern mostly the luminescent properties of doped HfO-based nanostructures, while the optical properties of nominally pure hafnia with optically active centers of intrinsic origin are far from being sufficiently investigated. In this work, for the first time we have conducted research on the wide-range temperature effects in the photoluminescence processes of anion-defective hafnia nanotubes with an amorphous and monoclinic structure, synthesized by the electrochemical oxidation method.
View Article and Find Full Text PDFChemistry
November 2024
Fachbereich Chemie, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Peter-Grünberg-Str. 12, 64287, Darmstadt, Germany.
3D carbon nanotube hybrid materials containing VO and VO evenly distributed onto vertically aligned carbon nanotubes (VACNTs) is reported. Adjustable loading of particles in controllable sizes and shapes onto the VACNTs was developed via a stepwise chemical vapour deposition (CVD) approach. Solid VO(acac) is chosen as vanadium source.
View Article and Find Full Text PDFAdv Mater
October 2024
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, P. R. China.
Aqueous Mn-ion batteries (MIBs) exhibit a promising development potential due to their cost-effectiveness, high safety, and potential for high energy density. However, the development of MIBs is hindered by the lack of electrode materials capable of storing Mn ions due to acidic manganese salt electrolytes and large ion radius. Herein, the tunnel-type structure of monoclinic VO nanorods to effectively store Mn ions via a reversible (de)insertion chemistry for the first time is reported.
View Article and Find Full Text PDFMaterials (Basel)
July 2024
Advanced Institute of Manufacturing with High-Tech Innovations and Department of Mechanical Engineering, National Chung Cheng University, 168 University Rd., Minhsiung Township 621301, Chiayi County, Taiwan.
Vanadium redox flow batteries (VRFBs) are of considerable importance in large-scale energy storage systems due to their high efficiency, long cycle life and easy scalability. In this work, chemical vapor deposition (CVD) grown carbon nanotubes (CNTs)-modified electrodes and Nafion 117 membrane are utilised for formulating a vanadium redox flow battery (VRFB). In a CVD chamber, the growth of CNTs is carried out on an acid-treated graphite felt surface.
View Article and Find Full Text PDFChem Commun (Camb)
April 2024
Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241002, PR China.
Electrode materials optimization is one of the keys to improving the energy storage characteristics of secondary batteries. Herein, a VO@carbon@SnS composite is developed by coating SnS quantum dots (QDs) on lamellar VO@carbon nanorods, yielding a high-performance aluminum-ion battery cathode. SnS QDs embedded in VO@carbon accelerate electron transport, while the coating of carbon improves cycling stability.
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