We consider the correlation between static conductivity and dynamic dielectric relaxation in a number of polar organic liquids. Experimental evidence suggests that in the simple cases the linear dependence between characteristic frequency of relaxation process and the value of static susceptibility is observed. However, this proportionality can be broken due to the appearance of additional relaxation processes (secondary or high-frequency ones) so it can be confused with the "fractional" variant of Debye-Stokes-Einstein relation.
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http://dx.doi.org/10.1063/1.4914185 | DOI Listing |
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