Formation and liquid permeability of dense colloidal cube packings.

Phys Rev E Stat Nonlin Soft Matter Phys

Van 't Hoff Laboratory for Physical and Colloid Chemistry, Debye Institute for Nanomaterials Science, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands.

Published: February 2015

The liquid permeability of dense random packings of cubic colloids with rounded corners is studied for solid hematite cubes and hollow microporous silica cubes. The permeabilities of these two types of packings are similar, confirming that the micropores in the silica shell of the hollow cubes do not contribute to the permeability. From the Brinkman screening length √k of ∼16 nm, we infer that the relevant pores are indeed intercube pores. Furthermore, we relate the permeability to the volume fraction and specific solid volume of the cubes using the Kozeny-Carman relation. The Kozeny-Carman relation contains a constant that accounts for the topology and size distribution of the pores in the medium. The constant obtained from our study with aspherical particles is of the same order of magnitude as those from studies with spherical and ellipsoidal particles, which supports the notion that the Kozeny-Carman relation is applicable for any dense particle packing with (statistically) isotropic microstructures, irrespective of the particle shape.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevE.91.022311DOI Listing

Publication Analysis

Top Keywords

kozeny-carman relation
12
liquid permeability
8
permeability dense
8
formation liquid
4
permeability
4
dense colloidal
4
colloidal cube
4
cube packings
4
packings liquid
4
dense random
4

Similar Publications

Different modeling techniques can be used to estimate the saturated conductivity of a porous medium based on computed tomography (CT) images. In this research, two methods are intercompared: direct modeling using the Navier-Stokes (NS) approach and simplified geometry pore network (PN) modeling. Both modeling approaches rely on pore media geometry which was determined using an X-ray CT scans with voxel size 2 μm.

View Article and Find Full Text PDF

Geochemical processes change the microstructure of rocks and thereby affect their physical behaviour at the macro scale. A micro-computer tomography (micro-CT) scan of a typical reservoir sandstone is used to numerically examine the impact of three spatial alteration patterns on pore morphology, permeability and elastic moduli by correlating precipitation with the local flow velocity magnitude. The results demonstrate that the location of mineral growth strongly affects the permeability decrease with variations by up to four orders in magnitude.

View Article and Find Full Text PDF

Evolution of saturated hydraulic conductivity with compression and degradation for municipal solid waste.

Waste Manag

July 2017

Yuhangtang Road 866#, MOE Key Laboratory of Soft Soils and Geoenvironmental Engineering, Institute of Geotechnical Engineering, Zhejiang University, Hangzhou 310058, China. Electronic address:

Municipal solid waste (MSW) specimens were created from synthetic fresh MSW degraded in a laboratory scale enhanced degradation reactor. The degree of degradation and saturated hydraulic conductivity k were measured to study the effects of compression and degradation on k of MSW. The degree of degradation was characterized through the ratio of cellulose content to lignin content (i.

View Article and Find Full Text PDF

This study was oriented toward the disintegration profiling of the diclofenac sodium (DS) immediate-release (IR) tablets and development of its relationship with medium permeability k based on Kozeny-Carman equation. Batches (L1-L9) of DS IR tablets with different porosities and specific surface area were prepared at different compression forces and evaluated for porosity, in vitro dissolution and particle-size analysis of the disintegrated mass. The k was calculated from porosities and specific surface area, and disintegration profiles were predicted from the dissolution profiles of IR tablets by stripping/residual method.

View Article and Find Full Text PDF

Formation and liquid permeability of dense colloidal cube packings.

Phys Rev E Stat Nonlin Soft Matter Phys

February 2015

Van 't Hoff Laboratory for Physical and Colloid Chemistry, Debye Institute for Nanomaterials Science, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands.

The liquid permeability of dense random packings of cubic colloids with rounded corners is studied for solid hematite cubes and hollow microporous silica cubes. The permeabilities of these two types of packings are similar, confirming that the micropores in the silica shell of the hollow cubes do not contribute to the permeability. From the Brinkman screening length √k of ∼16 nm, we infer that the relevant pores are indeed intercube pores.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!