AI Article Synopsis
- The first tritopic carborane-based linker, H3BCA, has been successfully synthesized and integrated into a metal-organic framework (MOF) called NU-700.
- Unlike MOF-143, NU-700 maintains its porosity even after activation.
- This process results in a high BET surface area of 1870 m² g⁻¹, indicating its potential for various applications.
Article Abstract
The first tritopic carborane-based linker, H3BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu3(BCA)2). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m(2) g(-1).
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| http://dx.doi.org/10.1039/c4cc09212k | DOI Listing |
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