An ultra-low Pd loading nanocatalyst with efficient catalytic activity.

Nanoscale

Laboratory for Large-format Battery Materials and Systems, Advanced Optoelectronic/Energy Materials and Inter-face Chemistry Joint Laboratory, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China.

Published: March 2015

AI Article Synopsis

  • * By modifying the shapes of Pd nanoclusters on zinc oxide (ZnO) nanorods, researchers found that a very small amount of Pd (0.05 at%) significantly improves the photocatalytic abilities of the nanocatalyst.
  • * The effectiveness of the Pd-ZnO hybrid nanocatalyst is demonstrated through its ability to reduce 4-nitrophenol to 4-aminophenol, providing insights into how the unique structure of the nanocatalyst affects its catalytic performance.

Article Abstract

An ultra-low Pd loading nanocatalyst is synthesized by a convenient solution route of photochemical reduction and aqueous chemical growth. The modification of nanocatalyst structures is investigated through changing morphologies of Pd nanoclusters on the surface of ZnO nanorods. A significant enhancement in photocatalytic properties has been achieved by decorating a trace amount of Pd clusters (0.05 at%) on the surface of ZnO nanorods. The reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) is applied to demonstrate multiple catalytic activities in the Pd-ZnO hybrid nanocatalyst, which also provides a better understanding of the relationship between the unique nanoconfigured structure and catalytic performance.

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Source
http://dx.doi.org/10.1039/c5nr00599jDOI Listing

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