A one-pot tandem Wittig/conjugate reduction/Paal-Knorr reaction is reported for the synthesis of di- or trisubstituted furans. This novel sequence first demonstrates the possibility of successively recycling waste from upstream steps to catalyze downstream reactions.
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http://dx.doi.org/10.1021/acs.orglett.5b00442 | DOI Listing |
Materials (Basel)
January 2025
Management Faculty, AGH University, Gramatyka 10 Str., 30-067 Kraków, Poland.
Additive manufacturing is a technology that creates objects by adding successive layers of material. The 3D method is an alternative to subtractive production, in which production involves removing material from the initial solid. 3D printing requires the initial design of the manufactured object using computer design, for example, one of the following programs: CAD, 3DCrafter, Wings 3D, Cinema 3, Blender, 3ds Max, Autodesk Inventor, and others.
View Article and Find Full Text PDFChemSusChem
January 2025
Spanish Scientific Research Council: Consejo Superior de Investigaciones Cientificas, Metalurgia Primaria y Reciclado de Materiales, SPAIN.
This work aims to recover rare earths from wind turbines NdFeB magnets through pyrometallurgical and hydrometallurgical techniques. First, a NdFeB hydride powder is obtained by decrepitation with hydrogen. Subsequently, this powder was subjected to a chlorination roasting process and successive leaching with water to bring the metals into solution.
View Article and Find Full Text PDFChemistry
January 2025
Centre CEA Paris-Saclay: Commissariat a l'Energie Atomique et aux Energies Alternatives Centre de Saclay, IRAMIS Institute, CEA - Saclay, 91190, Gif-Sur-Yvette, FRANCE.
The Schwartz's reagent Cp2Zr(H)Cl is a well known stoichiometric reagent for the reduction of unsaturated organic molecules but it has rarely been used in catalytic transformations. Herein, we describe the reduction of a variety of organic carbonates using the catalyst Cp2Zr(H)Cl in combination with Me(MeO)2SiH (DMMS) as reductant. This method was further applied to the reductive depolymerization of some polycarbonate materials and yielded silylated alcohols and diols in mild conditions.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Department of Applied Mathematics, Materials Science and Engineering and Electronic Technology, Universidad Rey Juan Carlos, Calle Tulipán s/n, 28933 Móstoles, Spain.
This work investigates the sustainable reuse of expanded polystyrene (EPS) waste through a multi-cycle physical recycling process involving dissolution in acetone and subsequent manufacturing via Direct Ink Write (DIW) 3D printing and casting. Morphology and mechanical properties were evaluated as a function of the manufacturing technique and number of dissolution cycles. Morphological analysis revealed that casted specimens better replicated the target geometry, while voids in 3D-printed specimens aligned with the printing direction due to rapid solvent evaporation.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Ernst-Berl-Institute of Technical and Macromolecular Chemistry, Technical University of Darmstadt, Peter-Grünberg-Straße 8, 64287 Darmstadt, Germany.
Hyper-cross-linked polymers (HCPs) enable the tailored synthesis of functionalized materials and provide a versatile design strategy for porous macroligands. Based on the prototypical triphenylphosphine (PPh) monomer, we investigate the role of the involved cross-linking reagents in the formation of polyphosphines and evaluate structure-activity relations for application in the catalytic CO hydrogenation: namely by varying the Friedel-Crafts catalyst, the cross-linker unit and the degree of cross-linking. The study of monomeric reactivities shows that phosphines are insufficiently activated by iron chloride catalyzed cross-linking and that the stronger aluminum chloride is required to ensure PPh incorporation.
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