A Cu-doped zeolite ZSM-5 (Cu-ZSM-5-M) with a micro-meso-macroporous structure was directly synthesized, and it exhibits excellent catalytic activity and good recyclability in the cross-coupling of aryl halides with diphenyl disulfides. This feature should be attributed to the structural characteristics of meso-macropores and homogeneous dispersion of active Cu(δ+) (δ < 2) species in Cu-ZSM-5-M.
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Article Synopsis
- Cross-coupling reactions are defined by regiospecificity, meaning the bond formation site is influenced by the position of the leaving group.
- Researchers propose a new method to create multiple structural isomers from the same coupling partners instead of synthesizing new isomer starting materials.
- The study demonstrates the use of a bulky palladium catalyst to enable efficient transposition of aryl halides, allowing high yields of unconventional product isomers through dynamic kinetic resolution combined with various nucleophiles.
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