A methylcarbonato ruthenium complex was prepared by capture of CO2 from air using the (CNC)(bpy)Ru scaffold. The methylcarbonato complex was relatively inert to decarboxylation. Treatments with methylating reagents released dimethylcarbonate.
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Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation.
Dalton Trans
March 2015
Division of Chemistry and Materials Science, Graduate School of Engineering, Nagasaki University, Bunkyo-machi 1-14, Nagasaki 852-8521, Japan.
A methylcarbonato ruthenium complex was prepared by capture of CO2 from air using the (CNC)(bpy)Ru scaffold. The methylcarbonato complex was relatively inert to decarboxylation. Treatments with methylating reagents released dimethylcarbonate.
View Article and Find Full Text PDFCarboxylate and alkyl carbonate coordination at the hydrophobic binding site of redox-active dicobalt amine thiophenolate complexes.
Inorg Chem
March 2002
Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstrasse 21, D-79104 Freiburg, Germany.
A series of new dicobalt complexes of the permethylated macrocyclic hexaamine dithiophenolate ligand H(2)L(Me) have been prepared and investigated in the context of ligand binding and oxidation state changes. The octadentate ligand is an effective dinucleating ligand that supports the formation of bioctahedral complexes with a central N(3)Co(mu-SR)(2)(mu-X)CoN(3) core structure, leaving a free bridging position X for the coordination of the substrates. The acetato- and cinnamato-bridged complexes [(L(Me))Co(II)(2)(mu-O(2)CMe)](+) (2) and [(L(Me))Co(II)(2)(mu-O(2)CCH=CHPh)](+) (5) were prepared by reaction of the mu-Cl complex [(L(Me))Co(II)(2)(mu-Cl)](+) (1) with the corresponding sodium carboxylates in methanol.
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