Macrocyclic compounds M1-M3 with different ring sizes containing amide and triazole units were synthesized. These triazolophanes displayed a variety of self-assembled structures such as hemi-toroids, toroids, and vesicles in a concentration dependent manner. Detailed ultramicroscopic and crystallographic investigations delineated a hierarchical mechanism of self-assembly.
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| http://dx.doi.org/10.1039/c4cc09587a | DOI Listing |
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