Exploring metal nanoclusters for lithium-oxygen batteries.

α-MnO2 nanowires modified with dispersed poly(3,4-ethylenedioxythiophene)-protected Au and Ag nanoclusters (Au-MnO2 and Ag-MnO2) were used for the first time as hybrid oxygen electrocatalysts for nonaqueous lithium-oxygen batteries. The Au-MnO2 and Ag-MnO2 hybrid catalysts surpassed the performance of pristine α-MnO2 nanowires in full-cell tests in the following order: Au-MnO2 > Ag-MnO2 > pristine α-MnO2. Specifically, cells with the Au-MnO2 catalyst could reduce the discharge/charge overpotentials at 100 mA g(-1) to 0.23/1.02 V and deliver discharge/charge capacities of 5784/5020 mAh g(-1). They could also be cycled for at least 60 times at the depth of discharge of 1000 mAh g(-1). The good full cell performance demonstrated the effectiveness of Au/Ag nanoclusters in promoting oxygen electrocatalysis on α-MnO2; forming discharge products with more reactive morphologies. It is therefore worthwhile to explore the use of Au and Ag nanoclusters in other catalyst systems for oxygen electrocatalysis in nonaqueous solutions.