Properties of spray pyrolised ZnO:Sn thin films and their antibacterial activity.

Tin doped zinc oxide (ZnO:Sn) thin films were deposited onto glass substrates by the spray pyrolysis technique with the substrate temperature 400 °C. The structural, optical, photoluminescence (PL) properties and morphological studies were investigated for the films deposited with various doping concentration (0, 2, 4, 6 and 8 at.%) of tin. The XRD results had shown that the films were polycrystalline ZnO with hexagonal wurtzite type structure and the crystallites in the films were oriented along (002) direction. Surface morphology of the films obtained by scanning electron microscope (SEM) exhibited the change in morphology with doping concentration and porous nature for the film with 6 at.% of tin. Atomic force microscopy (AFM) revealed nanometer sized particles with decreased surface roughness for Sn doping. Optical analysis exhibited the band gap value of 2.8 eV for ZnO:Sn (6 at.%) which was lower than the band gap value for undoped ZnO film (3.2 eV). The resistivity of 6 at.% of Sn doped film was 1.28×10(2) Ω cm with increase in the hall mobility and carrier concentration. The ZnO and Sn doped ZnO thin films exhibited antibacterial activity against Staphylococcus aureus.