Solution-processed organohalide perov-skite photodiodes that have performance metrics matching silicon, but are infrared-blind are reported. The perovskite photodiodes operate in the visible band, have low dark current and noise, high specific detectivity, large linear dynamic range, and fast temporal response. Their properties make them promising candidates for imaging applications.
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http://dx.doi.org/10.1002/adma.201405171 | DOI Listing |
Polymers (Basel)
January 2025
Department of Electrical and Biological Physics, Kwangwoon University, Wolgye-Dong, Seoul 01897, Republic of Korea.
Hybrid organohalide perovskites have received considerable attention due to their exceptional photovoltaic (PV) conversion efficiencies in optoelectronic devices. In this study, we report the development of a highly sensitive, self-powered perovskite-based photovoltaic photodiode (PVPD) fabricated by incorporating a poly(amic acid)-polyimide (PAA-PI) copolymer as an interfacial layer between a methylammonium lead iodide (CHNHPbI, MAPbI) perovskite light-absorbing layer and a poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT: PSS) hole injection layer. The PAA-PI interfacial layer effectively suppresses carrier recombination at the interfaces, resulting in a high power conversion efficiency () of 11.
View Article and Find Full Text PDFACS Nano
December 2024
Interuniversity Microelectronics Center (imec), Leuven 3001, Belgium.
Small
January 2025
Frontiers Science Center for Flexible Electronics (FSCFE), Shaanxi Institute of Flexible Electronics (SIFE) & Shaanxi Institute of Biomedical Materials and Engineering (SIBME), Northwestern Polytechnical University, Xi'an, 710129, China.
Metal halide perovskites have attracted significant attention in photodetection due to their superior photophysical properties and improved stability. However, the performance of their photodiodes is predominantly limited by non-radiative recombination within the perovskite layer or at interfaces. Here, molecular engineering via phenylethylammonium chloride for interfacial modulation and methylenediammonium dichloride for bulk modulation is introduced into vertical perovskite photodiodes to boost the photodetection performance.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2024
School of Electronic Science and Engineering, Southeast University, Nanjing 210000, China.
Lead halide perovskite single crystals (LHPSC) are promising for room-temperature γ-ray spectroscopy in radiation detection. While MA(CHNH)-based LHPSCs are the most straightforward and cost-effective to synthesize from solution, their performance in γ-ray spectroscopy is hindered by significant noise and ion migration at high bias, which degrades their energy resolution (ER). The work introduced an n-type/intrinsic/n-type photodiode incorporating passivation layers of MA-based LHPSCs, grown through solution-process epitaxial growth.
View Article and Find Full Text PDFAdv Mater
November 2024
School of Microelectronics, University of Science and Technology of China, Hefei, 230026, China.
Soft X-ray imaging is a powerful tool to explore the structure of cells, probe material with nanometer resolution, and investigate the energetic phenomena in the universe. Conventional soft X-ray image sensors are by and large Si-based charge coupled devices that suffer from low frame rates, complex fabrication processes, mechanical inflexibility, and required cooling below -60 °C. Here, a soft X-ray photodiode is reported based on low-cost metal halide perovskite with comparable performance to commercial Si-based device.
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