We describe a method for the creation of an efficient optical scatter trap by using fully crystalline octahedral Silicon nanoparticles (Si-NPs) of approximately 100 nanometres in size. The light trapping, even when probing an isolated nanoparticle, is revealed by an enormous amplification of the Raman yield of up to 10(8) times that of a similar Si bulk volume. The mechanism conceived and optimised for obtaining such a result was related to the capability of a Si octahedron to trap the light because of its geometrical parameters. Furthermore, Si-NPs act as very efficient light scatterers not only for the direct light beam but also for the trapped light after it escapes the nanoparticle. These two effects are observed, either superimposed or separated, by means of the Raman yield and by photoluminescence enhancements. The inductively coupled plasma synthesis process performed at a temperature of only 50 °C allows for the ubiquitous use of these particles on several substrates for optical and photovoltaic applications.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5389026 | PMC |
http://dx.doi.org/10.1038/srep08354 | DOI Listing |
Objectives: To assess the contemporary malignancy rate in isolated de novo red patches in the bladder and associated risk factors for better selection of red patch biopsy.
Patients: Patients from the IDENTIFY dataset; Patients referred to secondary care with suspected urinary tract cancer and found to have isolated de novo red patches on cystoscopy.
Methods: We reported the unadjusted cancer prevalence in isolated de novo red patches that were biopsied; multivariable logistic regression was used to explore cancer-associated risk factors including age, sex, smoking, type of haematuria, LUTS, UTIs and a suspicious-looking red patch (as reported by the cystoscopist).
Flow Turbul Combust
November 2024
Institut de Mécanique des Fluides de Toulouse, IMFT, CNRS, Université de Toulouse, Toulouse, France.
Improving mixing between two coaxial swirled jets is a subject of interest for the development of next generations of fuel injectors. This is particularly crucial for hydrogen injectors, where the separate introduction of fuel and oxidizer is preferred to mitigate the risk of flashback. Raman scattering is used to measure the mean compositions and to examine how mixing between fuel and air streams evolves along the axial direction in the near-field of the injector outlet.
View Article and Find Full Text PDFMar Pollut Bull
January 2025
Faculty of Marine Resources and Environment, Tokyo University of Marine Science and Technology, Konan 4-5-7, Minato-Ku, Tokyo 108-8477, Japan. Electronic address:
Microplastic pollution in marine environments poses significant environmental risks due to its widespread presence. Traditional micro-imaging measurement of microplastics often rely on post-cruise laboratory analyses. In this study, we explored the feasibility of onboard microplastic measurement using Raman spectroscopy, with a focus on polyethylene (PE).
View Article and Find Full Text PDFPharmaceutics
January 2025
Dipartimento di Scienze e Tecnologie Biologiche Chimiche e Farmaceutiche (STEBICEF), University of Palermo, Via Archirafi 32, 90123 Palermo, Italy.
Inorg Chem
January 2025
Center for Hierarchical Waste Form Materials, University of South Carolina, Columbia, South Carolina 29208, United States.
Ionic liquids were used as low temperature solvents for the synthesis of new lanthanide and transuranic-element (TRU) borate cluster structures. Ionothermal synthesis with the ionic liquid [BMIm]Cl (1-butyl-3-methylimidazolium chloride) yielded the La, Nd, and Am containing phases LaBOCl, NdBOCl, and AmBOCl. The structures of the La, Nd, and Am borate clusters were determined by single crystal X-ray diffraction (SCXRD) and found to be cubic, in the chiral space group 23.
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