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Orthogonal halogen and hydrogen bonds involving a peptide bond model†Electronic supplementary information (ESI) available: Experimental part, DSC, IR spectroscopic and crystallographic data. CCDC 899779-899785. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4ce01514bClick here for additional data file.Click here for additional data file. | LitMetric
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Orthogonal halogen and hydrogen bonds involving a peptide bond model†Electronic supplementary information (ESI) available: Experimental part, DSC, IR spectroscopic and crystallographic data. CCDC 899779-899785. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4ce01514bClick here for additional data file.Click here for additional data file.

Vera Vasylyeva Susanta K Nayak Giancarlo Terraneo Gabriella Cavallo Pierangelo Metrangolo Giuseppe Resnati

CrystEngComm

NFMLab , D.C.M.I.C. "Giulio Natta" , Politecnico di Milano , Via Mancinelli 7 , 20131 Milan , Italy . Email: ; Email: ; ; Tel: (+39) 02 2399 3041 ; Center for Nano Science and Technology@Polimi, Istituto Italiano di Tecnologia , Via Pascoli 70/3 , 20133 Milan , Italy.

Published: September 2014

AI Article Synopsis

  • The peptide bond model in methylacetamide indicates its ability to self-assemble with various dihalotetrafluorobenzenes.
  • This self-assembly leads to the formation of co-crystals, which are solid crystals containing two or more different molecules.
  • The resulting co-crystals exhibit the unique feature of orthogonal hydrogen and halogen bonding interactions.

Article Abstract

The peptide bond model -methylacetamide self-assembles with a range of dihalotetrafluorobenzenes forming co-crystals that all show the occurrence of orthogonal hydrogen and halogen bonds.

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 Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4317971PMC
http://dx.doi.org/10.1039/c4ce01514bDOI Listing

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