Moisture is an important variable that must be kept under control to guarantee a safe operation of power transformers. Because of the hydrophilic character of cellulose, water mainly remains in the solid insulation, while just a few parts per million are dissolved in oil. The distribution of moisture between paper and oil is not static, but varies depending on the insulation temperature, and thus, water migration processes take place continuously during transformers operation. In this work, a sensor is presented that allows the determination of the moisture content of the transformer solid insulation in the steady state and during the moisture migration processes. The main objective of the design is that the electrodes of the sensor should not obstruct the movement of water from the solid insulation to the oil, so the proposed prototype uses a metallic-mesh electrode to do the measurements. The measurement setup is based on the characterization of the insulation dielectric response by means of the frequency dielectric spectroscopy (FDS) method. The sensitivity of the proposed sensor has been tested on samples with a moisture content within 1% to 5%, demonstrating the good sensitivity and repeatability of the measurements.
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http://dx.doi.org/10.3390/s150203610 | DOI Listing |
Nano Lett
January 2025
Institut für Festkörperelektronik, Technische Universität Wien, Gußhausstraße 25, 1040 Vienna, Austria.
We synthesized and spectroscopically investigated monolayer (ML) C on the topological insulator (TI) BiTe. This C/BiTe heterostructure is characterized by an excellent translational order in a novel (4 × 4) C superstructure on a (9 × 9) cell of BiTe. Angle-resolved photoemission spectroscopy (ARPES) of C/BiTe reveals that ML C accepts electrons from the TI at room temperature, but no charge transfer occurs at low temperatures.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
University of Fribourg Faculty of Science: Universite de Fribourg Faculte de sciences et de medecine, Adolphe Merkle Institue, Chemin des Verdiers 4, 1700, Fribourg, SWITZERLAND.
Metal halide perovskites have shown exceptional potential in converting solar energy to electric power in photovoltaics, yet their application is hampered by limited operational stability. This stimulated the development of hybrid layered (two-dimensional, 2D) halide perovskites based on hydrophobic organic spacers, templating perovskite slabs, as a more stable alternative. However, conventional organic spacer cations are electronically insulating, resulting in charge confinement within the inorganic slabs, thus limiting their functionality.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Latvian State Institute of Wood Chemistry, Dzerbenes Street 27, LV-1006 Riga, Latvia.
The use of black alder (BA) bark biomass in rigid polyurethane (PUR) foam compositions was the main task of investigation. Extractive compounds isolated from the bark through hot water extraction were used as precursors for bio-polyol synthesis via acid-free liquefaction with the polyether polyol Lupranol 3300 and through oxypropylation with propylene carbonate. The OH functionality and composition of the polyols were analyzed via wet chemistry and FTIR spectroscopy.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
LAPLACE, Université de Toulouse, CNRS, INPT, UPS, 31077 Toulouse, France.
Fracto-emission is the ejection of electrons and positive ions from matter undergoing a mechanical fracture. The creation and propagation of fractures in insulating material can generate an electrical signal that can be detected using a sufficiently fast signal recorder. The theoretical equations related to crack creation/propagation that induce an externally electric signal are detailed for two conditions: with and without an external applied electric voltage.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
January 2025
Department of Physics, The University of Tokyo, Bunkyo-ku, Tokyo 113-0033, Japan.
The pseudogap phenomena have been a long-standing mystery of the cuprate high-temperature superconductors. The pseudogap in the electron-doped cuprates has been attributed to band folding due to antiferromagnetic (AFM) long-range order or short-range correlation. We performed an angle-resolved photoemission spectroscopy study of the electron-doped cuprates PrLaCeCuO showing spin-glass, disordered AFM behaviors, and superconductivity at low temperatures and, by measurements with fine momentum cuts, found that the gap opens on the unfolded Fermi surface rather than the AFM Brillouin zone boundary.
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