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Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers. | LitMetric
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Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers.

José Manuel Villalba Franco Takahiro Sasamori Gregor Schnakenburg Arturo Espinosa Ferao Rainer Streubel

Chem Commun (Camb)

Institut für Anorganische Chemie der Reinischen Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Str.1, 53121 Bonn, Germany.

Published: March 2015

Reaction of a Li/Cl phosphinidenoid complex with N,N'-dialkyl carbodiimides yielded the novel 3-imino-azaphosphiridine complexes; reaction with water led selectively to the first stable valence isomer of an oxaphosphirane complex.

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 Source
http://dx.doi.org/10.1039/c4cc10266eDOI Listing

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