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Base-mediated decomposition of amide-substituted furfuryl tosylhydrazones: synthesis and cytotoxic activities of enynyl-ketoamides. | LitMetric
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Base-mediated decomposition of amide-substituted furfuryl tosylhydrazones: synthesis and cytotoxic activities of enynyl-ketoamides.

Fanghua Ji Hui Peng Xiaoting Zhang Wenhua Lu Shubin Liu Huanfeng Jiang Bo Liu Biaolin Yin

J Org Chem

School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510006, P.R. China.

Published: February 2015

Base-mediated decomposition of amide-substituted furfuryl tosylhydrazones afforded practical access to novel multifunctionalized enynyl-ketoamides. In addition, furfuryl tosylhydrazones with stable furan rings underwent an interesting tosyl-group migration to form sulfones, which have potential synthetic applications. Some of the obtained enynyl-ketoamides demonstrated good cytotoxicities against human tumor cell lines.

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http://dx.doi.org/10.1021/jo502328jDOI Listing

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