PEG-imbedded PEO membrane developed by a novel highly efficient strategy toward superior gas transport performance.

Macromol Rapid Commun

State Key Laboratory of Urban Water Resource and Environment (SKLUWRE), School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, 150001, P.R. China.

Published: March 2015

AI Article Synopsis

  • - Low-molecular-weight poly(ethylene glycol) (PEG) is added to swellable poly(ethylene oxide) (PEO) membranes to enhance their performance in CO2 separation.
  • - The modified membranes show increased CO2 permeability and CO2/H2 selectivity due to their improved microstructure and higher fractional free volume.
  • - This research aims to advance the development of effective polymer membranes for clean energy applications, potentially bridging the gap between academic research and industrial use.

Article Abstract

Low-molecular-weight poly(ethylene glycol) (PEG) is deliberately incorporated into synthesized swellable poly(ethylene oxide) (PEO) membranes via a facile post-treatment strategy. The membranes exhibit both larger fractional free volume (FFV) and a higher content of CO2-philic building units, resulting in significant increments in both CO2 permeability and CO2/H2 selectivity. The separation performance correlates nicely with the microstructure of the membranes. This study may provide useful insights in the formation and mass transport behavior of highly efficient polymeric membranes applicable to clean energy purification and CO2 capture, and possibly bridge the material-induced technology gap between academia and industry.

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Source
http://dx.doi.org/10.1002/marc.201400633DOI Listing

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