Mesoporous Mn-Zr composite oxides (M-MnZr) with a crystalline wall were designed and achieved by a facile one-pot evaporation-induced self-assembly (EISA) strategy. As proved by XRD, HRTEM and SAED characterization, the wall of the obtained mesoporous materials exhibited a typical tetragonal phase of ZrO2. In addition, the introduced manganese species were homogeneously dispersed in the mesoporous skeleton. N2-physisorption and TEM results showed that all the final materials possessed an obvious mesoporous structure accompanied by a large specific surface area (∼120 m(2) g(-1)), big pore volume (∼0.2 cm(3) g(-1)) and uniform pore size (∼4.9 nm). In addition, the liquid phase oxidation was chosen as the test reaction and the excellent catalytic performance of M-MnZr demonstrated their potential applications in oxidation reactions.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c4dt03835e | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Guiding Transition Metal-Doped Hollow Cerium Tandem Nanozymes with Elaborately Regulated Multi-Enzymatic Activities for Intensive Chemodynamic Therapy.
Adv Mater
February 2022
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore, 637371, Singapore.
Clinical applications of nanozyme-initiated chemodynamic therapy (NCDT) have been severely limited by the poor catalytic efficiency of nanozymes, insufficient endogenous hydrogen peroxide (H O ) content, and its off-target consumption. Herein, the authors developed a hollow mesoporous Mn/Zr-co-doped CeO tandem nanozyme (PHMZCO-AT) with regulated multi-enzymatic activities, that is, the enhancement of superoxide dismutase (SOD)-like and peroxidase (POD)-like activities and inhibition of catalase (CAT)-like activity. PHMZCO-AT as a H O homeostasis disruptor promotes H O evolution and restrains off-target elimination of H O to achieve intensive NCDT.
View Article and Find Full Text PDFMesoporous Mn-Zr composite oxides with a crystalline wall: synthesis, characterization and application.
Dalton Trans
February 2015
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, People's Republic of China.
Mesoporous Mn-Zr composite oxides (M-MnZr) with a crystalline wall were designed and achieved by a facile one-pot evaporation-induced self-assembly (EISA) strategy. As proved by XRD, HRTEM and SAED characterization, the wall of the obtained mesoporous materials exhibited a typical tetragonal phase of ZrO2. In addition, the introduced manganese species were homogeneously dispersed in the mesoporous skeleton.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!