Temperature dependence of aging kinetics of hectorite clay suspensions.

The aging of salt-free hectorite suspensions with different concentrations (c(L)=2.9, 3.2 and 3.5 wt%) stored for 2 days or 4 days was studied by rheology at different temperatures. The evolution of storage and loss moduli G' and G″ during aging followed aging time-temperature superposition. The temperature dependence of the shift factor a(T), which reflected the aging kinetics, was interpreted by the reaction-limited colloidal aggregation (RLCA) mechanism with counterion condensation in calculating the double-layer interaction of the charged clay particles. Temperature dependence of the plateau modulus and yield stress of the suspension aged for 800 s was modeled with the soft glassy rheology (SGR) theory. The estimated noise temperature x indicated that the sample aged at higher temperature corresponded to a deeper quench in the nonergodic state. Under larger amplitude of oscillatory shear, the suspension exhibited a strain rate-frequency superposition (SRFS). The shearing eliminated the effects of aging and heating.