AI Article Synopsis
- Researchers developed a simple one-pot method to create mesoionic carbene boranes from 1,2,3-triazolium salts, a base, and borane.
- The process generates borenium ions, which are important intermediates formed by removing a hydride.
- These borenium ions act as catalysts for effective hydrogenation reactions of imines and unsaturated N-heterocycles under mild conditions, like room temperature and normal pressure.
Article Abstract
1,2,3-Triazolylidene-based mesoionic carbene boranes have been synthesized in a convenient one-pot protocol from the corresponding 1,2,3-triazolium salts, base, and borane. Borenium ions are obtained by hydride abstraction and serve as catalysts in mild hydrogenation reactions of imines and unsaturated N-heterocycles at ambient pressure and temperature.
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| http://dx.doi.org/10.1002/anie.201409250 | DOI Listing |
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