Synthesis and characterization of secondary nitrosamines from secondary amines using sodium nitrite and p-toluenesulfonic acid.

Chem Asian J

Laboratoire Hydrazines et Composés Ènergétiques Polyazotés, UMR 5278/CNRS/UCBL/CNES/SME-SAFRAN, Université Claude Bernard Lyon 1, 3è étage, 22, av. Gaston Berger, 69622 Villeurbanne (France), Fax: (+33) 472-431-291.

Published: March 2015

We synthesized nitrosamines (R2N-NO) with R = iPr (1), nPr (2), nBu (3), and hydroxyethyl (4) from the amine using sodium nitrite/p-toluenesulfonic acid in CH2Cl2. The rate of formation of 1-4 increases in the direction iPr

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http://dx.doi.org/10.1002/asia.201403182DOI Listing

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