Dual-emitting MOF⊃dye composite for ratiometric temperature sensing.

Adv Mater

State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China.

Published: February 2015

A strategy to achieve a ratiometric thermometer by encapsulating luminescent perylene dye into the pores of a europium metal-organic framework (MOF) is developed. The resulting MOF⊃dye thermometer exhibits highly temperature-dependent luminescence intensity ratio over the physiological temperature range, with a maximum sensitivity of 1.28% °C(-1) at 20 °C.

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http://dx.doi.org/10.1002/adma.201404700DOI Listing

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