Integration of rigid and flexible organic parts for the construction of a homochiral metal-organic framework with high porosity.

Chem Commun (Camb)

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.

Published: February 2015

Presented is a pair of homochiral metal-organic frameworks built from mixed ligands integrating rigid and flexible organic parts, and each compound shows high porosity and can be used for enantioselective separation of racemic 1-phenethylalcohol and methyl lactate.

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http://dx.doi.org/10.1039/c4cc09821hDOI Listing

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