The first enantioselective total synthesis of (-)-nardoaristolone B is accomplished by the implementation of an enantio- and diastereoselective copper(I)-catalyzed conjugate addition/enolate trapping sequence and a gold(I)-catalyzed oxidative cyclization (intermolecular oxidant), employed for the first time in total synthesis.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4322447 | PMC |
| http://dx.doi.org/10.1021/ol503531n | DOI Listing |
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