Definitive crystal structure of 1,1'-bis-[1,2-dicarba-closo-dodeca-borane(11)].

Acta Crystallogr Sect E Struct Rep Online

Institute of Chemical Sciences, Perkin Building, School of Engineering & Physical Sciences, Heriot Watt University, Edinburgh EH14 4AS, Scotland.

Published: December 2014

In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C-C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257441PMC
http://dx.doi.org/10.1107/S1600536814023897DOI Listing

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