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Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis. | LitMetric
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Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis.

Jonathan Potier Stéphane Menuel David Mathiron Véronique Bonnet Frédéric Hapiot Eric Monflier

Beilstein J Org Chem

Université Lille Nord de France, CNRS UMR 8181, Unité de Catalyse et de Chimie du Solide, UCCS Artois, Faculté Jean Perrin, rue Jean Souvraz, SP18, 62307 Lens Cédex, France.

Published: December 2014

New cyclodextrin (CD)-grafted polymers functionalized with water-soluble phosphanes were synthesized in three steps starting from polyNAS. Once characterized by NMR spectroscopy and size-exclusion chromatography, they were used as additives in Rh-catalyzed hydroformylation of 1-hexadecene. The combined supramolecular and coordinating properties of these polymers allowed increasing the catalytic activity of the reaction without affecting the selectivities.

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 Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273264PMC
http://dx.doi.org/10.3762/bjoc.10.276DOI Listing

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