The influence of methyl mercaptan on the repair bond strength of composites fabricated using self-etch adhesives was investigated. The surface free-energies were determined by measuring the contact angles of test liquids placed on composites that had been immersed in different concentrations of methyl mercaptan (0.01, 0.1, and 1.0 M). To determine the repair bond strength, self-etch adhesives were applied to the aged composite, and then newly added composites were condensed. Ten samples of each specimen were subjected to shear testing at a crosshead speed of 1.0 mm min(-1). Samples were analyzed using two-way ANOVA followed by Tukey's honestly significant difference (HSD) test. Although the dispersion force of the composites remained relatively constant, their polar force increased slightly as the concentration of methyl mercaptan increased. The hydrogen-bonding forces were significantly higher after immersion in 1.0 M methyl mercaptan, leading to higher surface-free energies. However, the repair bond strengths for the repair restorations prepared from composites immersed in 1.0 M methyl mercaptan were significantly lower than for those immersed in 0.01 and 0.10 M methyl mercaptan. Considering the results of this study, it can be concluded that the repair bond strengths of both the aged and newly added composites were affected by immersion in methyl mercaptan solutions.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1111/eos.12164 | DOI Listing |
Commun Biol
January 2025
Georgia Cancer Center, Augusta University, Augusta, GA, 30912, USA.
The transsulfuration (TSS) pathway is an alternative source of cysteine for glutathione synthesis. Little of the TSS pathway in antioxidant capacity in sickle cell disease (SCD) is known. Here, we evaluate the effects of TSS pathway activation through cystathionine beta-synthase (CBS) to attenuate reactive oxygen species (ROS) and ferroptosis stresses in SCD.
View Article and Find Full Text PDFSci Rep
December 2024
Graduate School of Bioagricultural Sciences, Nagoya University, Nagoya, 464-8601, Japan.
The bioluminescence reaction of firefly luciferase with D-luciferin has become an indispensable imaging technique in modern biology and life science experiments, but the high cost of D-luciferin is limiting its further application. Here, we report a practical, one-pot synthesis of D-luciferin from p-benzoquinone (p-BQ), L-cysteine methyl ester and D-cysteine, with an overall yield of 46%. Our route, which is six steps in length and proceeds via 2-cyano-6-hydroxybenzothiazole, is inspired by the mechanistic study of our previously reported biomimetic, non-enzymatic, one-pot formation of L-luciferin from p-BQ and L-cysteine.
View Article and Find Full Text PDFSci Total Environ
January 2025
UNSW Water Research Centre, School of Civil and Environmental Engineering, UNSW, Sydney, NSW 2052, Australia.
Anaerobic co-digestion is emerging as an option for wastewater biosolids management. Variations in treatment parameters can impact odour emissions and, in turn, odour nuisance reduces community acceptance and alternatives for beneficial reuse of biosolids via land application. This study assessed odour emissions from digested sludge and biosolids resulting from the anaerobic co-digestion of wastewater sludge with beverage rejects (beer and cola) and food wastes.
View Article and Find Full Text PDFInt Immunopharmacol
January 2025
Laboratory of Veterinary Pharmacology, School of Veterinary Medicine, Azabu University, 1-17-71 Fuchinobe, Chuo-ku, Sagamihara-shi, Kanagawa 252-5201, Japan; Center for Human and Animal Symbiosis Science, Azabu University, Sagamihara, Kanagawa, Japan. Electronic address:
It has been postulated that 90 % of cats and dogs develop periodontal disease by 1 year of age. Periodontal disease develops because of infection by multiple bacteria, including Porphyromonas gulae (P. gulae) and Porphyromonas gingivalis (P.
View Article and Find Full Text PDFOpen Biol
December 2024
Department of Food Science, Faculty of Agrobiology, Food and Natural Resources, Czech University of Life Sciences Prague, Prague, Czech Republic.
Intensive agricultural practices impact the health and nutrition of pollinators like honey bees (). Rapeseed ( L.) is widely cultivated, providing diverse nutrients and phytochemicals, including -methyl-L-cysteine sulfoxide (SMCSO).
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!