This review covers recently reported polymer composites that show a thermoelectric (TE) effect and thus have potential application as thermoelectric generators and Peltier coolers. The growing need for CO2-minimizing energy sources and thermal management systems makes the development of new TE materials a key challenge for researchers across many fields, particularly in light of the scarcity or toxicity of traditional inorganic TE materials based on Te and Pb. Recent reports of composites with inorganic and organic additives in conjugated and insulating polymer matrices are covered, as well as the techniques needed to fully characterize their TE properties.
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http://dx.doi.org/10.1002/anie.201408431 | DOI Listing |
Int J Biol Macromol
January 2025
Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, China; State Key Laboratory of Efficient Production of Forest Resources, Beijing Forestry University, Beijing 100083, China. Electronic address:
Due to the emphasis on the environmental and health issues caused by petroleum-based plastics, renewable lignocellulosic materials emerge as promising substitutes. However, their practical application remains hindered by unsatisfactory properties such as fragility and sensitivity to water. Dealing with the challenge of non-thermal processing of xylan and addressing the issue of performance degradation resulting from the hygroscopicity of materials.
View Article and Find Full Text PDFColloids Surf B Biointerfaces
December 2024
College of Physical, Sichuan University, Chengdu, Sichuan 610065, PR China. Electronic address:
The imbalance of redox homeostasis, especially the abnormal levels of reactive oxygen species (ROS), is a key obstacle in the bone repair process. Therefore, developing materials capable of scavenging ROS and modulating the microenvironment of bone defects is crucial for promoting bone repair. In this study, to endow poly(amino acids) (PAA) and its composites with anti-oxidative stress properties and enhanced osteogenic differentiation, we designed and prepared a calcium sulfate/calcium hydrogen phosphate/poly(amino acids) (PCDM) composite material with a thioether structure (-S-) in the molecular chain of PAA matrix through situ polymerization and physical blending method.
View Article and Find Full Text PDFSci Adv
January 2025
Department of Mechanical Engineering, University of Delaware, Newark, DE 19716, USA.
J Colloid Interface Sci
December 2024
Key Lab of Eco-Environments Related Polymer Materials of MOE, Key Lab of Bioelectrochemistry and Environmental Analysis of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Gansu International Scientific and Technological Cooperation Base of Water-Retention Chemical Functional Materials, Lanzhou 730070, PR China. Electronic address:
Transition metal sulfides (TMSs) have significant potential in energy storage applications due to their high theoretical capacity and diverse reaction mechanisms. However, performance limitations in supercapacitors arise from various intrinsic defects, including low active material utilization and poor cycling stability caused by unstable electrical conductivity. To address these issues, this paper incorporates selenium atoms into sulfides, aiming to leverage selenium's high conductivity to enhance the electroactivity of transition metal sulfides.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Yıldız Technical University, Department of Bioengineering, Davutpasa Campus, 34210 Esenler, İstanbul, Turkey.
The development of hybrid materials that integrate bioactive and antimicrobial properties within a biodegradable and biocompatible polymer matrix is a key focus in current biomedical research and applications. A significant research gap exists in the field of PHBV nanocomposites, particularly concerning those that simultaneously incorporate both ZnO and HAP particles. This study focuses on the fabrication and characterization of innovative hybrid bionanocomposites composed of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) combined with zinc oxide (ZnO) and silicon-doped hydroxyapatite (SiHAP) nanocrystals.
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