Control of 1,2- and 1,4-addition of substituted phenols to allylic oxides is achieved by intercepting palladium π-allyl complexes. The interconversion of palladium complexes results in the total synthesis of MK 7607, cyathiformine B type, streptol, and a new cyclitol.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4347901 | PMC |
| http://dx.doi.org/10.1002/anie.201410228 | DOI Listing |
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