AI Article Synopsis
- The study introduces a method for O-arylation of 1,2-aminoalcohols using specialized triarylbismuth compounds.
- The reaction can be conducted with minimal copper acetate and under mild conditions, making it more accessible.
- The process shows good compatibility with various functional groups, leading to the creation of diverse β-aryloxyamines while examining the role of the amino group in the reaction.
Article Abstract
The O-arylation of 1,2-aminoalcohols using functionalized triarylbismuth reagents is reported. The reaction can be performed using substoichiometric amounts of copper acetate and operates under mild conditions. Good functional group tolerance is observed, giving access to a range of β-aryloxyamines. The effect provided by the amino group in the arylation reaction is investigated.
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| http://dx.doi.org/10.1039/c4ob02497d | DOI Listing |
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