Positioning and switching phthalocyanine molecules on a Cu(100) surface at room temperature.

Reversible molecular switches with molecular orientation as the information carrier have been achieved on individual phthalocyanine (H2Pc) molecules adsorbed on a Cu(100) surface at room temperature. Scanning tunneling microscopy (STM) imaging directly demonstrates that H2Pc molecules can be controlled to move along the [011] or [011̅] surface direction of the Cu(100) surface, and the orientation of H2Pc molecules can also be switched between two angles of ±28° with respect to the [011] surface direction by a lateral manipulation. Owing to the highly efficient control over the adsorption site and orientation of H2Pc adsorbed on the Cu(100) surface by lateral manipulation, a pyramidal array formed by 10 H2Pc molecules has been constructed on the Cu surface as a prototype of binary memory, and every molecule within such a molecular array can be individually and reversibly controlled by a STM tip.