The synthesis and structural characterization is reported for [Fe(dien)2][FeSe2]2 and [Fe(tren)][FeSe2]2, two new mixed-valence compounds that contain infinite ∞(1)(FeSe2) tetrahedral chains separated by Fe-amine complexes. The inter- and intra-chain magnetic interactions can be controlled by changing the denticity of the amine while preserving the general structural motif.
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We report the use of the reported Fe-phthalocyanine complex, PcFe (; Pc = 1,4,8,11,15,18,22,25-octaethoxy-phthalocyanine), to generate PcFe-amine complexes , , and . Treatment of or to an excess of the stable aryloxide radical, 2,4,6-tri-butylphenoxyl radical (ArO), under NH resulted in catalytic H atom abstraction (HAA) and C-N coupling to generate the product 4-amino-2,4,6-tri-butylcyclohexa-2,5-dien-1-one () and ArOH. Exposing to an excess of the trityl (CPh) variant, 2,6-di--butyl-4-tritylphenoxyl radical (ArO), under NH did not lead to catalytic ammonia oxidation as previously reported in a related Ru-porphyrin complex.
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The synthesis and structural characterization is reported for [Fe(dien)2][FeSe2]2 and [Fe(tren)][FeSe2]2, two new mixed-valence compounds that contain infinite ∞(1)(FeSe2) tetrahedral chains separated by Fe-amine complexes. The inter- and intra-chain magnetic interactions can be controlled by changing the denticity of the amine while preserving the general structural motif.
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