Crystal templating through liquid-liquid phase separation.

Chem Commun (Camb)

School of Chemistry, WestCHEM, University of Glasgow, Glasgow G12 8QQ, UK.

Published: January 2015

Controlled induction of crystal nucleation is a highly desirable but elusive goal. Attempts to speed up crystallization, such as high super saturation or working near a liquid-liquid critical point, always led to irregular and uncontrollable crystal growth. Here, we show that under highly nonequilibrium conditions of spinodal decomposition, water crystals grow as thin wires in a template-less formation of "Haareis". This suggests that such nonequilibrium conditions may be employed more widely as mechanisms for crystal growth control.

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Source
http://dx.doi.org/10.1039/c4cc07880bDOI Listing

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