Rhodium-catalysed arylative annulation of 1,4-enynes with arylboronic acids.

Org Biomol Chem

Department of Applied Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.

Published: January 2015

The rhodium(I)-catalysed arylative annulation of 1,4-enynes with arylboronic acids was investigated. The reaction was found to proceed via an addition-1,4-rhodium migration-addition sequence, affording the corresponding 1,1-disubstituted 3-(arylmethylene)indanes.

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Source
http://dx.doi.org/10.1039/c4ob02210fDOI Listing

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