The so-called proximity effect is the manifestation, across an interface, of the systematic competition between magnetic order and superconductivity. This phenomenon has been well documented and understood for conventional superconductors coupled with metallic ferromagnets; however it is still less known for oxide materials, where much higher critical temperatures are offered by copper oxide-based superconductors. Here we show that, even in the absence of direct Cu-O-Mn covalent bonding, the interfacial CuO2 planes of superconducting La(1.85)Sr(0.15)CuO(4) thin films develop weak ferromagnetism associated to the charge transfer of spin-polarised electrons from the La(0.66)Sr(0.33)MnO(3) ferromagnet. Theoretical modelling confirms that this effect is general to all cuprate/manganite heterostructures and the presence of direct bonding only affects the strength of the coupling. The Dzyaloshinskii-Moriya interaction, also at the origin of the weak ferromagnetism of bulk cuprates, propagates the magnetisation from the interface CuO2 planes into the superconductor, eventually depressing its critical temperature.
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http://dx.doi.org/10.1038/ncomms6626 | DOI Listing |
Phys Chem Chem Phys
December 2024
Center of New Technologies, University of Warsaw, 02089 Warsaw, Poland.
Based on density functional theory calculations, we propose a new pathway toward compounds featuring flat [AgF] layers which mimic [CuO] layers in high-temperature oxocuprate superconductor precursors. Calculations predict the dynamic (phonon) and energetic stability of the new phases over diverse substrates. For some compounds with ferro orbital ordering, we find a gigantic intrasheet superexchange constant of up to -211 meV (DFT+) and -256 meV (SCAN), calculated for hypothetical (CsMgF)KAgF intergrowth.
View Article and Find Full Text PDFSci Rep
November 2024
Faculty of Science and Engineering, Waseda University, 2-2 Wakamatsu-cho, Shinjuku-ku, Tokyo, 162-8480, Japan.
Copper oxide high-temperature superconductors, such as BiSrCaCuO (Bi2212), have garnered extensive research interest due to their high critical temperatures (T) surpassing the Bardeen-Cooper-Schrieffer (BCS) limit. The two-dimensional CuO₂ plane is widely regarded as the most crucial element of high-T cuprate superconductors. The anisotropy of this CuO₂ layer remains a topic of ongoing interest.
View Article and Find Full Text PDFNat Commun
June 2024
Department of Physics, Okayama University, Okayama, Japan.
The mechanism of high-temperature superconductivity in copper oxides (cuprate) remains elusive, with the pseudogap phase considered a potential factor. Recent attention has focused on a long-range symmetry-broken charge-density wave (CDW) order in the underdoped regime, induced by strong magnetic fields. Here by Cu-nuclear magnetic resonance, we report the discovery of a long-range CDW order in the optimally doped BiSrLaCuO superconductor, induced by in-plane strain exceeding ∣ε∣ = 0.
View Article and Find Full Text PDFJ Chem Phys
June 2024
Department of Physics and Astronomy University of New Mexico, Albuquerque, New Mexico 87131, USA.
Uniquely, large-bipolarons' self-trapped holes occupy superoxygens, each comprising four oxygens circumscribed by four coppers in a CuO2 plane, formed as oxygens relax inward and coppers relax outward. Critically, concomitant oxygen-to-copper electron transfer eliminates copper spins. The d-symmetry of superoxygens' ground state molecular orbital tracks the superoxygens' predominant zero-point radial vibrations.
View Article and Find Full Text PDFNat Commun
August 2023
State Key Laboratory of Low Dimensional Quantum Physics and Department of Physics, Tsinghua University, Beijing, 100084, China.
Josephson tunneling in twisted cuprate junctions provides a litmus test for the pairing symmetry, which is fundamental for understanding the microscopic mechanism of high temperature superconductivity. This issue is rekindled by experimental advances in van der Waals stacking and the proposal of an emergent d+id-wave. So far, all experiments have been carried out on BiSrCaCuO (Bi-2212) with double CuO planes but show controversial results.
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