The present work introduces the study of the CO2 capture process by zeolites synthesized from paper sludge and scrap glass. Zeolites ZSM-5, analcime and wairakite were produced by means of two types of Structure Directing Agents (SDA): tetrapropilamonium (TPA) and ethanol. On the one hand, zeolite ZSM-5 was synthesized using TPA; on the other hand, analcime and wairakite were produced with ethanol. The temperature programmed desorption (TPD) technique was performed for determining the CO2 sorption capacity of these zeolites at two sorption temperatures: 50 and 100 °C. CO2 sorption capacity of zeolite ZSM-5 synthesized at 50 °C was 0.683 mmol/g representing 38.2% of the value measured for a zeolite ZSM-5 commercial. Zeolite analcime showed a higher CO2 sorption capacity (1.698 mmol/g) at 50 °C and its regeneration temperature was relatively low. Zeolites synthesized in this study can be used in the purification of biogas and this will produce energy without increasing the atmospheric CO2 concentrations.
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http://dx.doi.org/10.1177/0734242X14554643 | DOI Listing |
ChemistryOpen
January 2025
Department of Chemistry, University of Botswana, Botswana Private bag UB, Gaborone, 00704, Botswana.
This study explores the synthesis of ZSM-5 zeolite using high-purity mesoporous silica exclusively derived from coal fly ash (CFA), eliminating the need for additional silica or alumina sources. Traditional ZSM-5 synthesis relies on costly and environmentally harmful pure chemicals, whereas this approach utilizes CFA, an industrial byproduct, addressing both cost and sustainability concerns. The synthesized ZSM-5 zeolite demonstrates exceptional purity, with a surface area of 455.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
Yanshan Earth Critical Zone and Surface Fluxes Research Station, College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China. Electronic address:
Periodate (PI) activation via three-dimensional electrochemical (E) is a promising approach for degrading sulfisoxazole (SIZ), while the scarcity of active sites significantly limits the efficient electron-transfer rate. Herein, we synthesized multiple strongly active zero-valent cobalt (Co) nanoparticles encapsulated in nitrogen-doped carbon (NC) shells through Co-potassium chloride (KCl) doping pyrolysis of Zeolitic Imidazolate Framework-8 (ZIF-8) to induce the rapid electron transfer pathways (ETP). Specifically, molten KCl doping provides confined structures for Co with a diameter of 12.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Nanjing Tech University, College of Chemical Engineering, Nanjing, CHINA.
The wide application of zeolite Y in petrochemical industry is well known as one of the milestones in zeolite chemistry and heterogeneous catalysis. However, the traditional organic-free synthesis typically produces (hydro)thermally unstable zeolite Y with Si/Al atomic ratio (SAR) less than 2.5.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Food Engineering and Technology, Sant Longowal Institute of Engineering and Technology (SLIET), Longowal, 148106 Sangrur, Punjab, India. Electronic address:
In the present investigation, the formulation and thorough assessment of biodegradable composite films were conducted, utilizing pectin extracted from banana peel in conjunction with synthesized silver zeolite nanoparticles. The evaluation of physical properties, microstructural investigation, mechanical characteristics, and barrier properties was done providing valuable insights into various attributes of the film. The amalgamation of silver zeolite nanoparticles with the extracted pectin from banana peel results in biodegradable composite films exhibiting distinct physical, mechanical, barrier, and thermal properties.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
School of Petroleum and Natural Gas Engineering, Changzhou University, Changzhou 213164, China.
The development of copper-based materials with a high efficiency and low cost is desirable for use in iodine (I) remediation. Herein, Cu-nanoparticles-functionalized, ZIF-8 (Zeolite Imidazole Framework-8)-derived, nitrogen-doped carbon composites (Cu@Zn-NC) were synthesized by ball milling and pyrolysis processes. The as-prepared composites were characterized using SEM, BET, XRD, XPS, and FT-IR analyses.
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