An ink dating method based on solvent analysis was recently developed using thermal desorption followed by gas chromatography/mass spectrometry (GC/MS) and is currently implemented in several forensic laboratories. The main aims of this work were to implement this method in a new laboratory to evaluate whether results were comparable at three levels: (i) validation criteria, (ii) aging curves, and (iii) results interpretation. While the results were indeed comparable in terms of validation, the method proved to be very sensitive to maintenances. Moreover, the aging curves were influenced by ink composition, as well as storage conditions (particularly when the samples were not stored in "normal" room conditions). Finally, as current interpretation models showed limitations, an alternative model based on slope calculation was proposed. However, in the future, a probabilistic approach may represent a better solution to deal with ink sample inhomogeneity.
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http://dx.doi.org/10.1111/1556-4029.12603 | DOI Listing |
Surg Radiol Anat
December 2024
Department of Biomorphology, Federal University of Bahia, Salvador, Brazil.
Objective: The present study describes a rare anatomical variation of the anterior jugular vein (AJV) and discusses its clinical relevance.
Methods: A head and neck specimen fixed in 10% formaldehyde from a 42-year-old female cadaver was submitted to angio technique with pre-vulcanized latex and water-soluble ink. During a routine dissection for the discipline of topographic anatomy, the presence of an arcuate AJV was detected in the anterior triangle of the neck.
Spectrochim Acta A Mol Biomol Spectrosc
February 2025
Division of Forensic Sciences, Institute of Postgraduate Education, Istanbul Medeniyet University, 34700 Istanbul, Turkey; Department of Chemistry, Istanbul Medeniyet University, 34700 Istanbul, Turkey. Electronic address:
This study represents a methodology to determine the falsified documents via a combined method of spectroscopic techniques and chemometrics. The techniques of UV-Vis and FTIR-ATR spectroscopies and principal component analysis methods have been applied to black, blue, and red ballpoint pens available in the Türkiye market. The analysis results of the applied spectroscopic techniques were found to be consistent with each other for the examined eleven ink samples from three different brands, and it was observed that FTIR-ATR spectroscopy had higher discriminative power.
View Article and Find Full Text PDFAnal Chem
August 2024
Organic Geochemistry Unit, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, U.K.
Parchment is an ancient writing support formed from dehaired animal skins. Its manufacture comprises a series of liming and scraping steps before being stretched and dried under tension. Historical parchment represents a valuable source of cultural heritage which, until now, has limited investigations to noninvasive analyses to infer ink composition, degradation, or physical changes over time.
View Article and Find Full Text PDFCase Rep Dermatol
April 2024
Department of Dermatology, Inselspital, Bern University Hospital, University of Bern, Bern, Switzerland.
Introduction: Tattooing has a rich historical presence in various human civilizations, with the earliest physical evidence dating back to around 3258 BC. While acceptance of tattoos is increasing in the Western world, negative associations remain. Short-pulsed lasers, such as Q-Switched (QS) or picosecond lasers, are the gold standard for tattoo removal.
View Article and Find Full Text PDFAnal Methods
December 2023
Grupo de Pesquisa em Petróleo, Energia e Espectrometria de Massas (PEM), Departamento de Química, Universidade Federal Rural de Pernambuco - UFRPE, Rua Dom Manoel de Medeiros, s/n, Recife, Pernambuco, 52171-131, Brazil.
The dating of documents is crucial in forensic chemistry, particularly for verifying their authenticity. This study aimed to develop a rapid and direct method for the dating of pen ink in documents, using a combination of Fourier transform infrared spectroscopy in attenuated reflectance mode (FTIR-ATR), desorption electrospray ionization mass spectrometry (DESI-MS) and multiple ensemble data modeling. Two sets of paper document samples containing writing in blue pen ink were investigated: (I) artificially aged documents and (II) real documents dating from 1960 to 2022.
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