This paper investigates the adhesive interface in a polymer/metal (polyethylene terephthalate/steel) laminate that is subjected to uniaxial strain. Cross-sections perpendicular to such interfaces were created with a focused ion beam and imaged with scanning electron microscopy during straining in the electron microscope. During in situ straining, glide steps formed by the steel caused traction at the interface and initiated crazes in the polyethylene terephthalate (PET). These crazes readily propagated along the free surface of the PET layer. Similar crazing has not been previously encountered in laminates that were pre-strained or in numerical calculations. The impact of focused ion beam treatments on mechanical properties of the polymer/metal laminate system was therefore investigated. It was found that mechanical properties such as toughness of PET are dramatically influenced by focused ion beam etching. It was also found that this change in mechanical properties has a different effect on the pre-strained and in situ strained samples.
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http://dx.doi.org/10.1017/S1431927614013531 | DOI Listing |
Chem Asian J
January 2025
Chulalongkorn University, Chemistry, THAILAND.
This research focuses on the selective detection of Hg2+ ions using hybrid nanosensors composed of rhodamine building blocks linked to polyamine units of varying chain lengths to produce Rho1-Rho4, which were subsequently conjugated with thioctic acid (RT1-RT4) and attached to the surface of gold nanoparticles to create hybrid nanosensors (GRT1-GRT4) designed for detecting heavy metals. The chemical structures, purity, morphology, and chemical composition were characterized through XRD, NMR, TEM, ATR-FTIR, and mass spectrometry. These hybrid nanosensors demonstrated excellent selectivity and sensitivity in colorimetric and fluorescence responses towards Hg2+, outperforming other metal ions.
View Article and Find Full Text PDFMicroscopy (Oxf)
January 2025
Faculty of Engineering, Kyushu University, Fukuoka 819-0395, Japan.
Characterizing molten corium-concrete interaction (MCCI) fuel debris in Fukushima reactors is essential to develop efficient methods for its removal. To enhance the accuracy of microscopic observation and focused ion beam (FIB) microsampling of MCCI fuel debris, we developed a three-dimentional FIB scanning electron microscopy (SEM) technique with a multiphase positional misalignment (MPPM) correction method. This system automatically aligns voxel positions, corrects contrast, and removes artifacts from a series of over 500 SEM images.
View Article and Find Full Text PDFJ Mol Cell Cardiol
January 2025
Department of Physiology, University of Kentucky, Lexington, KY, USA; Department of Internal Medicine, University of Kentucky, Lexington, KY, USA. Electronic address:
Cardiologists have analyzed daily patterns in the incidence of sudden cardiac death to identify environmental, behavioral, and physiological factors that trigger fatal arrhythmias. Recent studies have indicated an overall increase in sudden cardiac arrest during daytime hours when the frequency of arrhythmogenic triggers is highest. The risk of fatal arrhythmias arises from the interaction between these triggers-such as elevated sympathetic signaling, catecholamine levels, heart rate, afterload, and platelet aggregation-and the heart's susceptibility (myocardial substrate) to them.
View Article and Find Full Text PDFAdv Colloid Interface Sci
January 2025
School of Metallurgy and Environment, Central South University, Changsha 410083, Hunan, China; Chinese National Engineering Research Center for Control & Treatment of Heavy Metal Pollution, Institute of Environmental Engineering, Central South University, Changsha 410083, Hunan, China.
Rare earth elements (REEs) are crucial metallic resources that play an essential role in national economies and industrial production. The reclaimation of REEs from wastewater stands as a significant supplementary strategy to bolster the REEs supply. Adsorption techniques are widely recognized as environmentally friendly and sustainable methods for the separation of REEs from wastewater.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Department of Mechanical Engineering, Chien-hsin University of Science and Technology, Taoyuan 320678, Taiwan.
Graphene's incorporation into polymers has enabled the development of advanced polymer/graphene nanocomposites with superior properties. This study focuses on the use of a microcellular foamed polystyrene (PS)/graphene (GP) nanocomposite (3 wt%) for nickel (II) ion removal from aqueous solutions. Adsorption behavior was evaluated through FTIR, TEM, SEM, TGA, and XRD analyses.
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