The hydrogels based on the co-assembly of bolaamphiphilic L-histidine and 2,2'-bipyridine-dicarboxylic acids were transformed into viscoelastic supramolecular polymers by cross-linking with Cu(II) ions, and macroscopic supramolecular yarns were obtained by direct drawing from a dilute aqueous solution of the supramolecular polymers.
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http://dx.doi.org/10.1039/c4cc07813f | DOI Listing |
Materials (Basel)
February 2024
ECOResearch Student Research Group, Faculty of Material Technologies and Textile Design, Lodz University of Technology, 116 Zeromskiego Str., 90-924 Lodz, Poland.
The application of biobased and biodegradable polymers, such as polylactide (PLA), in fused deposition modeling (FDM) 3D-printing technology creates a new prospect for rapid prototyping and other applications in the context of ecology. The popularity of the FDM method and its significance in material engineering not only creates new prospects for the development of technical sciences on an industrial scale, but also introduces new technologies into households. In this study, the kinetics of the hydrolytic degradation of samples obtained by the FDM method from commercially available PLA filaments under a thermally accelerated regime were analyzed.
View Article and Find Full Text PDFAdv Mater
May 2019
Fibre and Polymer Technology, KTH Royal Institute of Technology, 100 44 Stockholm, Sweden.
Organic semiconductors are the centerpiece of several vibrant research fields from single-molecule to organic electronics, and they are finding increasing use in bioelectronics and even classical polymer technology. The versatile chemistry and broad range of electronic functionalities of conjugated materials enable the bridging of length scales 15 orders of magnitude apart, ranging from a single nanometer (10 m) to the size of continents (10 m). This work provides a taste of the diverse applications that can be realized with organic semiconductors.
View Article and Find Full Text PDFChem Commun (Camb)
December 2014
Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, P. R. China.
The hydrogels based on the co-assembly of bolaamphiphilic L-histidine and 2,2'-bipyridine-dicarboxylic acids were transformed into viscoelastic supramolecular polymers by cross-linking with Cu(II) ions, and macroscopic supramolecular yarns were obtained by direct drawing from a dilute aqueous solution of the supramolecular polymers.
View Article and Find Full Text PDFAdv Mater
November 2013
Beijing National Laboratory for Molecular Science (BNLMS), CAS Key Laboratory of Colloid, Interface, and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.
Metric length supramolecular nanotube yarns are fabricated though a spinning process from the diluted aqueous solution of self-assembled nanotubes, with bolaamphiphiles working as molecular building blocks. These non-covalent bonding based nanotube yarns show outstanding mechanical strength compared with some conventional polymers and could be operated under the macro conditions.
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