Actual dimension control of silicon (Si) nanowire arrays was conducted using metal-assisted chemical etching on Si patterned by electron beam lithography. The appearance of nanogaps at the edge of each nanowire provides the diffusion pathways of reactants for Si dissolution, predominantly causing distinct etching rates that depend upon the spacings of nanogaps.
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http://dx.doi.org/10.1039/c4cp04237a | DOI Listing |
Polymers (Basel)
December 2024
Department of Chemical and Biological Engineering, Gachon University, 1342 Seongnamdaero, Sujeong-Gu, Seongnam-Si 13120, Gyeonggi-do, Republic of Korea.
Si anode materials are promising candidates for next-generation Li-ion batteries (LIBs) because of their high capacities. However, expansion and low conductivity result in rapid performance degradation. Herein, we present a facile one-pot method for pyrolyzing polystyrene sulfonate (PSS) polymers at low temperatures (≤400 °C) to form a thin carbonaceous layer on the silicon surface.
View Article and Find Full Text PDFMetals are an emerging topic in cancer immunotherapy that have shown great potential in modulating cancer immunity cycle and promoting antitumor immunity by activating the intrinsic immunostimulatory mechanisms which have been identified in recent years. The main challenge of metal-assisted immunotherapy lies in the fact that the free metals as ion forms are easily cleared during circulation, and even cause systemic metal toxicity due to the off-target effects. With the rapid development of nanomedicine, metal-based smart nanosystems (MSNs) with unique controllable structure become one of the most promising delivery carriers to solve the issue, owing to their various endogenous/external stimuli-responsiveness to release free metal ions for metalloimmunotherapy.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea.
Achieving precise and cost-effective etching in the field of silicon three-dimensional (3D) structure fabrication remains a significant challenge. Here, we present the successful fabrication of microscale anisotropic Si structures with an etching anisotropy of 0.73 using Cu-metal-assisted chemical etching (Cu-MACE) and propose a mechanism to elucidate the chemical behavior of Cu within the MACE solution.
View Article and Find Full Text PDFBiosens Bioelectron
January 2025
Sensor Engineering Department, Faculty of Science and Engineering, Maastricht University, P.O. Box 616, 6200 MD, Maastricht, the Netherlands.
Effective bacterial detection is crucial for health diagnostics, particularly for the detection of pathogenic species like Escherichia coli (E. coli), which is responsible for up to 90% of urinary tract infections (UTIs), is especially crucial. Current detection methods are time-consuming, often delaying diagnosis and treatment.
View Article and Find Full Text PDFSmall
November 2024
School of Integrated Technology, Yonsei University, Incheon, 21983, Republic of Korea.
Metal-assisted chemical etching (MACE), a wet-based anisotropic etching process for semiconductors, has emerged as an alternative to plasma-based etching. However, using noble metal catalysts in MACE limits the implementation of complementary metal-oxide-semiconductor (CMOS) processes. This study explores Si etching using an ultrathin Ni catalyst as a novel approach for MACE.
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