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Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I). | LitMetric
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Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I).

Byron J Truscott Fady Nahra Alexandra M Z Slawin David B Cordes Steven P Nolan

Chem Commun (Camb)

EaStCHEM, School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife KY16 9ST, UK.

Published: January 2015

Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir-bifluoride and Ir(I)-NHC and Rh(I)-NHC trifluoromethyl complexes are revealed.

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 Source
http://dx.doi.org/10.1039/c4cc07772eDOI Listing

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