We investigate the effect of multiwalled carbon nanotubes (MWCNTs) on the magnetorheological properties of an oil based magnetic nanofluid (ferrofluid). The shear resistant plateau observed in a pure ferrofluid disappears when 0.5 wt% of MWCNT is incorporated. The yield stress values of the composite system are slightly smaller than that of the pure system. This shows that the presence of carbon nanotubes (CNTs) weakens the magnetic field induced microstructure of the ferrofluid due to their interaction that affects the hydrodynamic and magnetic interactions between the dispersed nanoparticles. Interestingly, the Mason number plots for both the pure and composite system show scaling of the viscosity curves onto a single master curve for magnetic fields of 80 mT and above while deviations are observed for lower magnetic fields. The weakening of the ferrofluid microstructure in the presence of CNTs is further evident in the amplitude sweep measurements where the linear viscoelastic region develops only at a higher magnetic field strength compared to lower magnetic fields in pure ferrofluids. These results are useful for tailoring ferrofluids with a faster response for various applications.
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http://dx.doi.org/10.1103/PhysRevE.89.022310 | DOI Listing |
Turk J Chem
November 2024
School of Chemical and Blasting Engineering, Anhui University of Science and Technology, Huainan, P.R. China.
The development of ultraviolet (UV) shielding materials is of great importance to protect human health and prevent the degradation of organic matter. However, the synthesis of highly efficient UV shielding polymer nanocomposites is currently limited by the agglomeration of inorganic anti-UV nanoparticles (NPs) within the polymer matrix and the limited absorption spectrum of UV shielding agents. In this study, highly effective manganese doped carbon quantum dots@halloysite nanotube composites (Mn-CDs@HNTs/PAS) were successfully synthesized by loading manganese-doped carbon quantum dots (Mn-CDs) into UV shielding effective halloysite nanotubes (HNTs) via the solvothermal method, followed by polymerization modification (PAS).
View Article and Find Full Text PDFSmall
January 2025
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, 215123, China.
Bio-inspired by tactile function of human skin, piezoionic skin sensors recognize strain and stress through converting mechanical stimulus into electrical signals based on ion transfer. However, ion transfer inside sensors is significantly restricted by the lack of hierarchical structure of electrode materials, and then impedes practical application. Here, a durable nanocomposite electrode is developed based on carbon nanotubes and graphene, and integrated into piezoionic sensors for smart wearable applications, such as facial expression and exercise posture recognitions.
View Article and Find Full Text PDFBMC Chem
January 2025
National Organization for Drug Control and Research (NODCAR), P.O.Box 29, Cairo, Egypt.
Tirofiban hydrochloride is used to inhibit platelet aggregation, which has a significant impact on the treatment of congestive heart failure the most common cause of death according to WHO. Therefore, its quantification in pharmaceutical dosage form is critical. In this work, an electrochemical method for the determination of tirofiban HCl in pharmaceutical dosage form was developed and validated.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physics, Faculty of Science, Vali-e-Asr University of Rafsanjan, Rafsanjan, Iran.
To protect against harmful electromagnetic interference (EMI), it is crucial to fabricate composite with high total electromagnetic shielding efficiency (SE); In this study, FeNi-NiFeO-SiO nanoparticles (NPs) were synthesized using one-pot method and decorated on carbon nanotube's (CNT) sidewall. The final product was magnetic-ceramic/conductive (FeNi-NiFeO-SiO/MWCNT) nanocomposite. The EMI shielding characteristic of FeNi-NiFeO-SiO NPs and FeNi-NiFeO-SiO/MWCNT nanocomposite was investigated in the range of X and Ku frequency band.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
Beijing Key Laboratory of Lignocellulosic Chemistry, MOE Engineering Research Center of Forestry Biomass Materials and Energy, Beijing Forestry University, Beijing 100083, China; State Key Laboratory of Efficient Production of Forest Resources, Beijing 100083, China. Electronic address:
Integrating liquid metal (LM) with wood fibers for flexible paper electronics is intriguing yet extremely challenging due to poor mechanical performance. Here, we disclose a hemicellulose trapping strategy to achieve exceptional ultrastrong and tough LM-based paper electronics. Holocellulose nanofibrils (HCNFs) with hemicellulose retention of approximately 20 % are found to effectively entrap nanoscale LM within the fibril network, analogous to spider silk capturing small water droplets.
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