Noncovalently assembled nanotubular porous layers for delaying of heating surface failure.

Sci Rep

Active Materials and Smart Living (AMSL) Laboratory, Mechanical Engineering Department, University of Nevada, Las Vegas, Nevada 89154, USA.

Published: October 2014

Thermal management to prevent extreme heat surge in integrated electronic systems and nuclear reactors is a critical issue. To delay the thermal surge on the heater effectively, we report the benefit of a three dimensional nanotubular porous layer via noncovalent interactions (hydrophobic forces and hydrogen bonds). To observe the contribution of individual noncovalent interactions in a porous network formation, pristine carbon nanotubes (PCNTs) and oxidatively functionalized carbon nanotubes (FCNTs) were compared. Hydrogen-bonded interwoven nanotubular porous layer showed approximately two times critical heat flux (CHF) increase compared to that of a plain surface. It is assumed that the hydrophilic group-tethered nanotubular porous wicks and enhanced fluidity are the main causes for promoting the CHF increase. Reinforced hydrophilicity assists liquid spreading and capillarity-induced liquid pumping, which are estimated by using Electrochemical Impedance Spectroscopy. Also, shear induced thermal conduction, thermal boundary reduction, and rheology of nanoparticles could attribute to CHF enhancement phenomena.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4212230PMC
http://dx.doi.org/10.1038/srep06817DOI Listing

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