With the help of the ligand-oriented method, we have successfully embedded independent copper-based units into the indium-organic framework system for the first time, in which the Cu4I4 clusters and In3O(CO2)6 clusters coexist. This heterometallic cluster-based framework has a large porosity with extra-open channels along the c-axis, and its sorption capacity has also been investigated.
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http://dx.doi.org/10.1039/c4cc07611g | DOI Listing |
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