Heterometallic cluster-based indium-organic frameworks.

Chem Commun (Camb)

Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.

Published: December 2014

With the help of the ligand-oriented method, we have successfully embedded independent copper-based units into the indium-organic framework system for the first time, in which the Cu4I4 clusters and In3O(CO2)6 clusters coexist. This heterometallic cluster-based framework has a large porosity with extra-open channels along the c-axis, and its sorption capacity has also been investigated.

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Source
http://dx.doi.org/10.1039/c4cc07611gDOI Listing

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