Guest-responsive function of a dynamic metal-organic framework with a π Lewis acidic pore surface.

Chemistry

Department of Chemistry, Indian Institute of Science Education and Research (IISER) Pune, Dr. Homi Bhabha Road, Pashan, Pune-411008 (India), Fax: (+91) 2025908186 http://www.iiserpune.ac.in/∼sghosh/

Published: November 2014

A 3D dynamic coordination framework with an electron-deficient pore surface has been synthesized by using Zn(II) (having a variable coordination number) and a predesigned flexible π-electron-deficient core-based ligand, exhibiting chemical separations based on pore surface functionalization (π Lewis acidic pore surfaces and open metal sites) and framework flexibility, giving rise to a unique smart guest-responsive material.

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Source
http://dx.doi.org/10.1002/chem.201402855DOI Listing

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