In the title compound, C11H10N3OS(+)·Cl(-)·2H2O, the organic cation exhibits a dihedral angle of 21.26 (8)° between the mean planes of the pyridine and thio-phene rings, and dihedral angles of 15.11 (9) and 6.49 (9)° between the mean planes of the hydrazide moiety and the pyridine and thio-phene rings, respectively. In the crystal, the organic cation, the chloride counter-anion and the two water mol-ecules of crystallization are linked through an intricate hydrogen-bonding network consisting of O-H⋯O, O-H⋯N, N-H⋯Cl, C-H⋯Cl, C-H⋯O, N-H⋯O, O-H⋯Cl and C-H⋯S inter-actions that consolidate a three-dimensional network.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186149PMC
http://dx.doi.org/10.1107/S1600536814017565DOI Listing

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